|
|
(4S,8R)-2,19-dihydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1,3(10),5,11,14,16-hexaene-13,18,20-trione + O2 + NADPH + H+ <=> (4S,8R)-2,20-dihydroxy-7,9,13-trioxapentacyclo[10.9.0.03,10.04,8.015,20]henicosa-1,3(10),5,11,15,17-hexaene-14,19,21-trione + H2O + NADP+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21574
|
|
|
|
S-adenosyl-L-methionine + 6-demethylsterigmatocystin <=> H+ + S-adenosyl-L-homocysteine + sterigmatocystin
|
2.1.1.109
demethylsterigmatocystin 6-O-methyltransferase
|
–
|
| |
BRENDA:
BR43868
KEGG:
R03112
MetaCyc:
2.1.1.109-RXN
|
|
|
|
16-deoxyversicolorin_A_epoxide <=> (4S,8R)-2,19-dihydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1,3(10),5,11,14,16-hexaene-13,18,20-trione
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21582
|
|
|
|
(4S,8R)-2,20-dihydroxy-7,9,13-trioxapentacyclo[10.9.0.03,10.04,8.015,20]henicosa-1,3(10),5,11,15,17-hexaene-14,19,21-trione <=> 6-demethylsterigmatocystin + CO2
|
4.1.1
|
–
|
| |
MetaCyc:
RXN-21575
|
|
|
|
16-deoxyversicolorin_A + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 16-deoxyversicolorin_A_epoxide + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-21581
|
|
|
|
(4S,8R,16R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.014,19]icosa-1(12),2,5,10,13,19-hexaen-18-one + acceptor <=> 16-deoxyversicolorin_A + H2O + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21577
|
|
|
|
(4S,8R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1(12),2,5,10,13,16,19-heptaen-18-one + NADPH + H+ <=> (4S,8R,16R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.014,19]icosa-1(12),2,5,10,13,19-hexaen-18-one + NADP+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN-21576
|
|
|
|
Versicolorin_A + reduced_acceptor + H+ <=> (4S,8R)-2,13,16,20-tetrahydroxy-7,9-dioxapentacyclo[10.8.0.03,10.04,8.04,19]icosa-1(12),2,5,10,13,16,19-heptaen-18-one + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21578
|
|
|
|
versicolorin_B + NADP+ <=> Versicolorin_A + NADPH + H+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN-9495
|
|
