|
|
2-hydroxymethylglutarate <=> 2-Methyleneglutarate + H2O
|
not assigned
|
–
|
| |
KEGG:
R07986
MetaCyc:
RXN-7640
|
|
|
|
nicotinate + H2O + NADP+ <=> 6-Hydroxynicotinate + NADPH + H+
|
1.17.1.5
nicotinate dehydrogenase
|
–
|
| |
BRENDA:
BR48018
KEGG:
R01720
MetaCyc:
RXN-7637
|
|
|
|
(R)-3-methylitaconate <=> dimethylmaleate
|
5.3.3.6
methylitaconate Delta-isomerase
|
–
|
| |
BRENDA:
BR4
KEGG:
R03070
MetaCyc:
METHYLITACONATE-DELTA-ISOMERASE-RXN
|
|
|
|
1,4,5,6-Tetrahydro-6-oxonicotinate + oxidized_ferredoxin <=> 6-Hydroxynicotinate + reduced_ferredoxin_[iron-sulfur]_cluster + H+
|
1.3.7.1
6-hydroxynicotinate reductase
|
–
|
| |
BRENDA:
BR36846
KEGG:
R03164
MetaCyc:
6-HYDROXYNICOTINATE-REDUCTASE-RXN
|
|
|
|
1,4,5,6-Tetrahydro-6-oxonicotinate + H2O <=> (S)-2-formylglutarate + NH3
|
3.5.2.18
enamidase
|
–
|
| |
BRENDA:
BR48770
KEGG:
R07984
MetaCyc:
3.5.2.18-RXN
|
|
|
|
2-Methyleneglutarate <=> (R)-3-methylitaconate
|
5.4.99.4
2-methyleneglutarate mutase
|
–
|
| |
BRENDA:
BR251;
BS368784
KEGG:
R03908
MetaCyc:
2-METHYLENEGLUTARATE-MUTASE-RXN
|
|
|
|
2-hydroxymethylglutarate + NAD+ <=> (S)-2-formylglutarate + NADH + H+
|
1.1.1.291
2-hydroxymethylglutarate dehydrogenase
|
–
|
| |
BRENDA:
BR48766
KEGG:
R07985
MetaCyc:
1.1.1.291-RXN
SABIO-RK:
14710
|
|
|
|
(2R,3S)-dimethylmalate <=> dimethylmaleate + H2O
|
4.2.1.85
dimethylmaleate hydratase
|
–
|
| |
BRENDA:
BR48334
KEGG:
R03069
MetaCyc:
DIMETHYLMALEATE-HYDRATASE-RXN
|
|
|
|
(2R,3S)-dimethylmalate <=> propionate + pyruvate
|
3.7.1.1
oxaloacetase
4.1.3.1
isocitrate lyase
4.1.3.32
2,3-dimethylmalate lyase
|
–
–
–
|
| |
BRENDA:
BR391;
BS1884
KEGG:
R01355
MetaCyc:
23-DIMETHYLMALATE-LYASE-RXN
|
|
