|
|
(2R,4E)-2-amino-5-({[(2S,3R)-2-hydroxy-3-(1H-indol-3-yl)butanamido]methanimidoyl}amino)pent-4-enoate + H+ <=> indolmycin_B + NH3
|
not assigned
|
–
|
| |
MetaCyc:
RXN-17536
|
|
|
|
L-tryptophan + pyruvate <=> 3-Indole-2-oxopropanoate + L-alanine
|
2.6.1.28
tryptophan---phenylpyruvate transaminase
2.6.1.44
alanine---glyoxylate transaminase
2.6.1.5
tyrosine transaminase
2.6.1.51
serine---pyruvate transaminase
2.6.1.57
aromatic-amino-acid transaminase
2.6.1.64
glutamine---phenylpyruvate transaminase
2.6.1.99
L-tryptophan---pyruvate aminotransferase
|
–
–
–
–
–
–
–
|
| |
BRENDA:
BR50308
KEGG:
R10180
MetaCyc:
RXN-10139
|
|
|
|
S-adenosyl-L-methionine + 3-Indole-2-oxopropanoate <=> S-adenosyl-L-homocysteine + (R)-3-(indol-3-yl)-2-oxobutanoate + H+
|
2.1.1.47
indolepyruvate C-methyltransferase
|
–
|
| |
BRENDA:
BR40566
KEGG:
R01972
MetaCyc:
RXN-17530
|
|
|
|
L-arginine + NAD+ <=> 4,5-dehydro-L-arginine + NADH + H+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN-17535
|
|
|
|
(2R,4E)-2-amino-5-({[(2S,3R)-2-hydroxy-3-(1H-indol-3-yl)butanamido]methanimidoyl}amino)pent-4-enoate <=> N-demethylindolmycin + (2S)-2-amino-5-iminopentanoate
|
4.3.3
|
–
|
| |
MetaCyc:
RXN-17532
|
|
|
|
ATP + (2S,3R)-2-hydroxy-3-(indol-3-yl)butanoate + 4,5-dehydro-L-arginine <=> (2R,4E)-2-amino-5-({[(2S,3R)-2-hydroxy-3-(1H-indol-3-yl)butanamido]methanimidoyl}amino)pent-4-enoate + AMP + diphosphate + H+
|
6.3.2
|
–
|
| |
MetaCyc:
RXN-17531
|
|
|
|
(2S,3R)-2-hydroxy-3-(indol-3-yl)butanoate + NAD+ <=> (R)-3-(indol-3-yl)-2-oxobutanoate + NADH + H+
|
1.1.1.397
beta-methylindole-3-pyruvate reductase
|
–
|
| |
BRENDA:
BR51636
KEGG:
R11336
MetaCyc:
RXN-17529
|
|
|
|
S-adenosyl-L-methionine + N-demethylindolmycin <=> S-adenosyl-L-homocysteine + indolmycin + H+
|
2.1.1.328
N-demethylindolmycin N-methyltransferase
|
–
|
| |
BRENDA:
BR51749
KEGG:
R11534
MetaCyc:
RXN-17534
|
|
|
|
H+ + H2O + L-pyrroline-5-carboxylate <=> L-glutamate_5-semialdehyde
|
0.0.0.0
|
–
|
| |
BRENDA:
BR52883
KEGG:
R03314
MetaCyc:
SPONTPRO-RXN
|
|
|
|
(2S)-2-amino-5-iminopentanoate + H2O + H+ <=> L-glutamate_5-semialdehyde + NH3
|
3.5.99
|
–
|
| |
MetaCyc:
RXN-17533
|
|
