|
|
UDP-glucose + (E)-omega-(methylsulfanyl)octyl-thiohydroximate <=> H+ + desulfo-7-methylthioheptyl_glucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
MetaCyc:
RXNQT-4327
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)octan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)octyl-thiohydroximate + L-seryl-glycine
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-11442
|
|
|
|
4-methylthiooctanaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-(methylsulfanyl)-8-aci-nitrooctane + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11418
|
|
|
|
(E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)octan-1-imine + H2O <=> (E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)octan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
MetaCyc:
RXN-11434
|
|
|
|
(E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)octan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)octyl-thiohydroximate + pyruvate + NH3
|
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
|
| |
MetaCyc:
RXNQT-4322
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-7-methylthioheptyl_glucosinolate <=> adenosine_3,5''-bisphosphate + H+ + 7-methylthioheptyl_glucosinolate
|
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
|
| |
BRENDA:
BS407935
KEGG:
R11887
MetaCyc:
RXNQT-4332
|
|
|
|
7-methylthioheptyl_glucosinolate + O2 + NADPH + H+ <=> 7-(methylsulfinyl)heptyl-glucosinolate + H2O + NADP+
|
1.14.13.237
aliphatic glucosinolate S-oxygenase
|
–
|
| |
MetaCyc:
RXNQT-4337
|
|
|
|
L-pentahomomethionine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 4-methylthiooctanaldoxime + CO2 + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
MetaCyc:
RXNQT-4312
|
|
|
|
1-(methylsulfanyl)-8-aci-nitrooctane + glutathione <=> (E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)octan-1-imine + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11426
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)octan-1-imine + H2O <=> (E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)octan-1-imine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19590
|
|
