|
|
dihydrophloroglucinol + H2O <=> 3-Hydroxy-5-oxohexanoate + H+
|
3.7.1
|
–
|
| |
KEGG:
R07831
MetaCyc:
R6-RXN
|
|
|
|
H+ + gallic_acid <=> CO2 + pyrogallol
|
4.1.1.59
gallate decarboxylase
4.1.1.61
4-hydroxybenzoate decarboxylase
|
–
–
|
| |
BRENDA:
BR319
KEGG:
R03247
MetaCyc:
GALLATE-DECARBOXYLASE-RXN
|
|
|
|
dihydrophloroglucinol + NADP+ <=> H+ + phloroglucinol + NADPH
|
1.3.1.57
phloroglucinol reductase
|
–
|
| |
BRENDA:
BR29437
KEGG:
R05308
MetaCyc:
R5-RXN
|
|
|
|
ATP + acetate <=> ADP + acetyl_phosphate
|
2.1.2.2
phosphoribosylglycinamide formyltransferase
2.7.2.1
acetate kinase
2.7.2.15
propionate kinase
2.7.2.2
carbamate kinase
|
–
–
–
–
|
| |
BRENDA:
BR47820
KEGG:
R00315
MetaCyc:
ACETATEKIN-RXN
SABIO-RK:
71
|
|
|
|
3-hydroxy-5-oxohexanoyl-CoA + CoA <=> (S)-3-hydroxybutyryl-CoA + acetyl-CoA
|
2.3.1
|
–
|
| |
KEGG:
R07833
MetaCyc:
R7-RXN
|
|
|
|
butyryl-CoA + NAD+ + reduced_ferredoxin_[iron-sulfur]_cluster <=> crotonyl-CoA + NADH + oxidized_ferredoxin
|
1.3.1.109
butanoyl-CoA dehydrogenase (NAD+, ferredoxin)
|
–
|
| |
BRENDA:
BR51444
KEGG:
R11675
MetaCyc:
RXN-16834
|
|
|
|
3-hydroxy-5-oxohexanoyl-CoA + acetate <=> 3-Hydroxy-5-oxohexanoate + acetyl-CoA
|
2.8.3.8
acetate CoA-transferase
|
–
|
| |
KEGG:
R07832
MetaCyc:
R8-RXN
|
|
|
|
1,2,3,5-Tetrahydroxybenzene + pyrogallol <=> 1,2,3,5-Tetrahydroxybenzene + phloroglucinol
|
1.97.1.2
pyrogallol hydroxytransferase
|
–
|
| |
BRENDA:
BR40344
KEGG:
R04297
MetaCyc:
1.97.1.2-RXN
|
|
|
|
(S)-3-hydroxybutyryl-CoA <=> H2O + crotonyl-CoA
|
1.3.8.7
medium-chain acyl-CoA dehydrogenase
4.2.1.116
3-hydroxypropionyl-CoA dehydratase
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
|
–
–
–
–
|
| |
BRENDA:
BR51003
KEGG:
R03026
MetaCyc:
RXN-11667;
RXN-15014
SABIO-RK:
2876
|
|
|
|
phosphate + acetyl-CoA <=> acetyl_phosphate + CoA
|
2.3.1.19
phosphate butyryltransferase
2.3.1.222
phosphate propanoyltransferase
2.3.1.8
phosphate acetyltransferase
|
–
–
–
|
| |
BRENDA:
BR44082
KEGG:
R00230
MetaCyc:
PHOSACETYLTRANS-RXN
SABIO-RK:
72
|
|
|
|
butyryl-CoA + acetate <=> Butyrate + acetyl-CoA
|
2.8.3.1
propionate CoA-transferase
2.8.3.14
5-hydroxypentanoate CoA-transferase
2.8.3.8
acetate CoA-transferase
2.8.3.9
butyrate---acetoacetate CoA-transferase
|
–
–
–
–
|
| |
BRENDA:
BS358809
KEGG:
R01179
MetaCyc:
R11-RXN
|
|
