|
|
hercynine + gamma-Glu-L-Cys + O2 <=> S-(hercyn-2-yl)-gamma-L-glutamyl-L-cysteine_S-oxide + H2O
|
1.14.99.50
gamma-glutamyl hercynylcysteine S-oxide synthase
|
–
|
| |
BRENDA:
BR51393
KEGG:
R11013
MetaCyc:
RXN-14430
|
|
|
|
L-glutamate + L-cysteine + ATP <=> gamma-Glu-L-Cys + ADP + phosphate + H+
|
6.3.2.2
glutamate---cysteine ligase
|
–
|
| |
BRENDA:
BR112
KEGG:
R00894
MetaCyc:
GLUTCYSLIG-RXN
SABIO-RK:
1217
|
|
|
|
S-(hercyn-2-yl)-L-cysteine_S-oxide + H2O <=> 2-(hydroxysulfanyl)-L-histidine + pyruvate + NH3
|
4.4.1.36
hercynylcysteine S-oxide lyase
|
–
|
| |
BRENDA:
BR52225
KEGG:
R11864
MetaCyc:
RXN-18088
|
|
|
|
S-adenosyl-L-methionine + L-histidine <=> hercynine + S-adenosyl-L-homocysteine + H+
|
2.1.1.44
L-histidine Nalpha-methyltransferase
|
–
|
| |
BRENDA:
BR50754
KEGG:
R01169
MetaCyc:
RXN-14431
|
|
|
|
S-(hercyn-2-yl)-gamma-L-glutamyl-L-cysteine_S-oxide + H2O <=> S-(hercyn-2-yl)-L-cysteine_S-oxide + L-glutamate
|
3.5.1.118
gamma-glutamyl hercynylcysteine S-oxide hydrolase
|
–
|
| |
BRENDA:
BR51309
KEGG:
R11021
MetaCyc:
RXN-14429
|
|
|
|
2-(hydroxysulfanyl)-L-histidine + reduced_acceptor <=> ergothioneine + acceptor + H2O
|
4.4.1.36
hercynylcysteine S-oxide lyase
|
–
|
| |
BRENDA:
BR52226
KEGG:
R11865
MetaCyc:
RXN-18089
|
|
|
|
ergothioneine_(thione_form) <=> ergothioneine
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15804
|
|
