|
|
4-coumaroyl-CoA + shikimate <=> 4-coumaroylshikimate + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.140
rosmarinate synthase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
|
BRENDA:
BR43994
KEGG:
R02416
MetaCyc:
2.3.1.133-RXN
|
|
|
|
4-coumaroyl-CoA + quinate <=> 5-O-p-coumaroylquinic_acid + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
|
|
BRENDA:
BS320439
KEGG:
R07432
MetaCyc:
RXN-2601
|
|
|
|
5-O-p-coumaroylquinic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> chlorogenic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
|
MetaCyc:
1.14.13.36-RXN
|
|
|
|
4-coumaroylshikimate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> trans-5-O-caffeoylshikimate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
|
MetaCyc:
RXN-2581
|
|