|
|
feruloyl-CoA + H2O <=> 4-hydroxy-3-methoxyphenyl-beta-hydroxypropionyl-CoA
|
4.1.2.61
feruloyl-CoA hydratase/lyase
4.2.1.101
trans-feruloyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BR22824
KEGG:
R05772
MetaCyc:
4.2.1.101-RXN
|
|
|
|
L-alanine + Vanillin <=> pyruvate + vanillylamine
|
2.6.1.119
vanillin aminotransferase
|
–
|
| |
BRENDA:
BR53079
KEGG:
R12622
MetaCyc:
RXN-8925
|
|
|
|
8-Methyl-6-nonenoate + CoA + ATP <=> (6E)-8-methylnon-6-enoyl-CoA + ADP + phosphate
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
| |
MetaCyc:
RXN-21443
|
|
|
|
malonyl-[acyl-carrier_protein] + isobutyryl-CoA + NADPH + H+ <=> 8-Methyl-6-nonenoate + [acyl-carrier_protein] + CoA + H2O + NADP+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-8926
|
|
|
|
4-hydroxy-3-methoxyphenyl-beta-hydroxypropionyl-CoA <=> acetyl-CoA + Vanillin
|
4.1.2.41
vanillin synthase
4.1.2.61
feruloyl-CoA hydratase/lyase
|
–
–
|
| |
BRENDA:
BR29122
KEGG:
R05773
MetaCyc:
4.1.2.41-RXN
|
|
|
|
(6E)-8-methylnon-6-enoyl-CoA + vanillylamine <=> capsaicin + CoA + H+
|
2.3.2.35
capsaicin synthase
|
–
|
| |
BRENDA:
BR53074
KEGG:
R12626
MetaCyc:
RXN-8927
|
|
|
|
S-adenosyl-L-methionine + caffeoyl-CoA <=> H+ + feruloyl-CoA + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
|
–
|
| |
BRENDA:
BR43863
KEGG:
R01942
MetaCyc:
CAFFEOYL-COA-O-METHYLTRANSFERASE-RXN
|
|
