|
|
L-methionine + a_2-oxo_carboxylate <=> 4-methylsulfanyl-2-oxobutanoate + proteinogenic_amino_acid
|
2.6.1.88
methionine transaminase
|
–
|
| |
MetaCyc:
R15-RXN
|
|
|
|
5-methylthio-2-oxopentanoate + proteinogenic_amino_acid <=> L-homomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
MetaCyc:
RXN-2205
|
|
|
|
2-[(2''-methylsulfanyl)ethyl]malate <=> 2-[(2''-methylsulfanyl)ethyl]maleate + H2O
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
BRENDA:
BS438076
MetaCyc:
RXN-18182
|
|
|
|
2-[(2''-methylsulfanyl)ethyl]maleate + H2O <=> 3-[(2''-methylsulfanyl)ethyl]malate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18183
|
|
|
|
2-[2-(methylsulfanyl)ethyl]-3-oxobutanedioate + H+ <=> 5-methylthio-2-oxopentanoate + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18198
|
|
|
|
4-methylsulfanyl-2-oxobutanoate + acetyl-CoA + H2O <=> 2-[(2''-methylsulfanyl)ethyl]malate + CoA + H+
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438092
KEGG:
R08619
MetaCyc:
RXN-2202
|
|
|
|
3-[(2''-methylsulfanyl)ethyl]malate + NAD+ <=> 2-[2-(methylsulfanyl)ethyl]-3-oxobutanedioate + NADH + H+
|
1.1.1
|
–
|
| |
MetaCyc:
RXN-2204
|
|
