|
|
(3S)-3-hydroxytetradecanoyl-CoA <=> 2-tetradecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BS2105
KEGG:
R04740
MetaCyc:
RXN-14273
SABIO-RK:
4396
|
|
|
|
(S)-3-hydroxydecanoyl-CoA <=> trans-2-decenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BS2103
KEGG:
R04744
MetaCyc:
RXN-13616
SABIO-RK:
4400
|
|
|
|
hexadecanal + NAD+ + H2O <=> fatty_acid + NADH + H+
|
1.2.1.3
aldehyde dehydrogenase (NAD+)
1.2.1.47
4-trimethylammoniobutyraldehyde dehydrogenase
1.2.1.48
long-chain-aldehyde dehydrogenase
1.2.1.5
aldehyde dehydrogenase [NAD(P)+]
|
–
–
–
–
|
| |
BRENDA:
BR36783
KEGG:
R01704;
R02039
MetaCyc:
LONG-CHAIN-ALDEHYDE-DEHYDROGENASE-RXN;
RXN-16655
SABIO-RK:
1816
|
|
|
|
acetyl-CoA + myristoyl-CoA <=> CoA + 3-ketohexadecanoyl-CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
| |
BRENDA:
BR29472
KEGG:
R03991
MetaCyc:
2.3.1.155-RXN;
RXN-16560
SABIO-RK:
3726
|
|
|
|
an_aldehyde + NAD+ + H2O <=> fatty_acid + NADH + H+
|
1.2.1.3
aldehyde dehydrogenase (NAD+)
1.2.1.5
aldehyde dehydrogenase [NAD(P)+]
|
–
–
|
| |
KEGG:
R00631
|
|
|
|
L-3-hydroxydodecanoyl-CoA + NAD+ <=> 3-oxododecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
KEGG:
R04741
MetaCyc:
RXN-20676
|
|
|
|
hexanoyl-CoA + acetyl-CoA <=> 3-oxooctanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
| |
BRENDA:
BS189545
KEGG:
R04747
MetaCyc:
RXN-14277
SABIO-RK:
4403
|
|
|
|
L-3-hydroxydodecanoyl-CoA <=> trans-2-dodecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BS2104
KEGG:
R04170
MetaCyc:
RXN-20675
SABIO-RK:
3890
|
|
|
|
octanoyl-CoA + FAD <=> 2-octenoyl-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.8.8
long-chain acyl-CoA dehydrogenase
1.3.99
|
–
–
–
–
|
| |
KEGG:
R03777
SABIO-RK:
3536
|
|
|
|
alkane + 2 reduced_rubredoxin + O2 + 2 H+ <=> 2 oxidized_rubredoxin + an_alcohol + H2O
|
1.14.15.3
alkane 1-monooxygenase
|
–
|
| |
KEGG:
R02281
|
|
|
|
decanoyl-CoA + FAD <=> trans-2-decenoyl-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.8.8
long-chain acyl-CoA dehydrogenase
1.3.99
|
–
–
–
–
|
| |
KEGG:
R04754
SABIO-RK:
4410
|
|
|
|
butyryl-CoA + acetyl-CoA <=> 3-oxohexanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
|
| |
BRENDA:
BS189544
KEGG:
R01177
MetaCyc:
RXN-12565
SABIO-RK:
1414
|
|
|
|
(S)-3-hydroxybutyryl-CoA <=> (3R)-hydroxybutyryl-CoA
|
5.1.2.3
3-hydroxybutyryl-CoA epimerase
|
–
|
| |
BRENDA:
BR180
KEGG:
R03276
MetaCyc:
5.1.2.3-RXN
|
|
|
|
cis,cis-3,6-Dodecadienoyl-CoA <=> trans,cis-Lauro-2,6-dienoyl-CoA
|
5.3.3.8
Delta3-Delta2-enoyl-CoA isomerase
|
–
|
| |
KEGG:
R04756
|
|
|
|
decanoyl-CoA + acetyl-CoA <=> 3-oxododecanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
| |
BRENDA:
BS189547
KEGG:
R04742
MetaCyc:
RXN-14274
SABIO-RK:
4398
|
|
|
|
an_alcohol + acceptor <=> an_aldehyde + reduced_acceptor
|
1.1.99.12
sorbose dehydrogenase
1.1.99.20
alkan-1-ol dehydrogenase (acceptor)
1.1.99.36
alcohol dehydrogenase (nicotinoprotein)
|
–
–
–
|
| |
BRENDA:
BR36750;
BR49366
KEGG:
R00639
MetaCyc:
ALKAN-1-OL-DEHYDROGENASE-ACCEPTOR-RXN;
RXN-21246
|
|
|
|
palmitoyl-CoA + FAD <=> trans-2-hexadecenoyl-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.8.8
long-chain acyl-CoA dehydrogenase
1.3.8.9
very-long-chain acyl-CoA dehydrogenase
1.3.99
|
–
–
–
–
–
|
| |
KEGG:
R01279
SABIO-RK:
1495
|
|
|
|
NAD+ + reduced_rubredoxin + H+ <=> NADH + oxidized_rubredoxin
|
1.18.1.1
rubredoxin---NAD+ reductase
1.18.1.3
ferredoxin---NAD+ reductase
1.18.1.4
rubredoxin---NAD(P)+ reductase
|
–
–
–
|
| |
BRENDA:
BR40365-a
KEGG:
R02000
MetaCyc:
RUBREDOXIN--NAD+-REDUCTASE-RXN;
RUBREDOXIN--NADP+-REDUCTASE-RXN_WOP
SABIO-RK:
2039
|
|
|
|
palmitoyl-CoA + L-carnitine <=> O-palmitoyl-L-carnitine + CoA
|
2.3.1.137
carnitine O-octanoyltransferase
2.3.1.21
carnitine O-palmitoyltransferase
2.3.1.7
carnitine O-acetyltransferase
|
–
–
–
|
| |
BRENDA:
BR44020;
BS320669;
BS435704
KEGG:
R01923
MetaCyc:
CARNITINE-O-PALMITOYLTRANSFERASE-RXN
SABIO-RK:
1977
|
|
|
|
fatty_acid + reduced_flavodoxin + O2 <=> omega-hydroxy_fatty_acid + flavin + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
BRENDA:
BS442561
KEGG:
R01348
|
|
|
|
(S)-3-hydroxyoctanoyl-CoA <=> 2-octenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BS2102
KEGG:
R04746
MetaCyc:
RXN-20678
SABIO-RK:
4402
|
|
|
|
fatty_acid + O2 + 2 reduced_rubredoxin + 2 H+ <=> omega-hydroxy_fatty_acid + 2 oxidized_rubredoxin + H2O
|
1.14.15.3
alkane 1-monooxygenase
|
–
|
| |
KEGG:
R01347
|
|
|
|
(3S)-hydroxyhexadecanoyl-CoA <=> trans-2-hexadecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BR451
KEGG:
R04738
MetaCyc:
LONG-CHAIN-ENOYL-COA-HYDRATASE-RXN;
RXN-14272
SABIO-RK:
4394
|
|
|
|
octanoyl-CoA + acetyl-CoA <=> 3-oxodecanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
| |
BRENDA:
BS189546
KEGG:
R03778
MetaCyc:
RXN-13617
SABIO-RK:
3537
|
|
|
|
(S)-3-hydroxyoctanoyl-CoA + NAD+ <=> 3-oxooctanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
BRENDA:
BS188060
KEGG:
R04745
MetaCyc:
RXN-20679
SABIO-RK:
4401
|
|
|
|
reduced_rubredoxin + NADP+ + H+ <=> oxidized_rubredoxin + NADPH
|
1.18.1.1
rubredoxin---NAD+ reductase
1.18.1.4
rubredoxin---NAD(P)+ reductase
|
–
–
|
| |
BRENDA:
BR40365
KEGG:
R02002
MetaCyc:
RUBREDOXIN--NADP+-REDUCTASE-RXN
SABIO-RK:
2040
|
|
|
|
butyryl-CoA + FAD <=> crotonyl-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
1.3.8.1
short-chain acyl-CoA dehydrogenase
1.3.8.4
isovaleryl-CoA dehydrogenase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.99
|
–
–
–
–
–
|
| |
BRENDA:
BS414397
KEGG:
R01175
SABIO-RK:
1412
|
|
|
|
NAD+ + hexadecanol <=> H+ + NADH + hexadecanal
|
1.1.1.1
alcohol dehydrogenase
1.1.1.164
hexadecanol dehydrogenase
1.1.1.192
long-chain-alcohol dehydrogenase
|
–
–
–
|
| |
BRENDA:
BR29227
KEGG:
R02462
MetaCyc:
HEXADECANOL-DEHYDROGENASE-RXN
|
|
|
|
myristoyl-CoA + FAD <=> 2-tetradecenoyl-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.8.8
long-chain acyl-CoA dehydrogenase
1.3.8.9
very-long-chain acyl-CoA dehydrogenase
1.3.99
|
–
–
–
–
–
|
| |
KEGG:
R03990
SABIO-RK:
3725
|
|
|
|
reduced_flavodoxin + fatty_acid + O2 <=> alpha-Hydroxy_fatty_acid + flavin + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
| |
KEGG:
R04121
|
|
|
|
an_alcohol + NAD+ <=> an_aldehyde + NADH + H+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.103
L-threonine 3-dehydrogenase
1.1.1.11
D-arabinitol 4-dehydrogenase
1.1.1.14
L-iditol 2-dehydrogenase
1.1.1.17
mannitol-1-phosphate 5-dehydrogenase
1.1.1.184
carbonyl reductase (NADPH)
1.1.1.192
long-chain-alcohol dehydrogenase
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.202
1,3-propanediol dehydrogenase
1.1.1.21
aldose reductase
1.1.1.244
methanol dehydrogenase
1.1.1.245
cyclohexanol dehydrogenase
1.1.1.284
S-(hydroxymethyl)glutathione dehydrogenase
1.1.1.306
S-(hydroxymethyl)mycothiol dehydrogenase
1.1.1.307
D-xylose reductase
1.1.1.6
glycerol dehydrogenase
1.1.1.71
alcohol dehydrogenase [NAD(P)+]
1.1.1.73
octanol dehydrogenase
1.1.1.77
lactaldehyde reductase
1.1.1.78
methylglyoxal reductase (NADH)
1.1.1.80
isopropanol dehydrogenase (NADP+)
1.1.1.B4
|
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR29164;
BS139564;
BS405084
KEGG:
R00623;
R00754;
R07326
MetaCyc:
ALCOHOL-DEHYDROG-GENERIC-RXN;
ALCOHOL-DEHYDROG-RXN;
ALCOHOL-DEHYDROGENASE-NADP+-RXN_WOP
SABIO-RK:
597
|
|
|
|
lauroyl-CoA + acetyl-CoA <=> 3-oxotetradecanoyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
| |
KEGG:
R03858
MetaCyc:
RXN-14268
|
|
|
|
fatty_acid + [acyl-carrier_protein] + ATP <=> palmitoyl-[acyl-carrier_protein] + AMP + diphosphate
|
6.2.1.20
long-chain-fatty-acid---[acyl-carrier-protein] ligase
|
–
|
| |
BRENDA:
BR72;
BS211;
BS214
KEGG:
R01406
MetaCyc:
ACYLACPSYNTH-RXN;
RXN-13267;
RXN-13268
|
|
|
|
fatty_acid + CoA + ATP <=> stearoyl-CoA + AMP + diphosphate
|
1.13.12.7
firefly luciferase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.30
phenylacetate---CoA ligase
6.2.1.B3
|
–
–
–
–
–
|
| |
BRENDA:
BR82;
BS287
KEGG:
R00390;
R01280
MetaCyc:
RXN-16380;
RXN-7904;
RXN-9623
SABIO-RK:
10953;
1496
|
|
|
|
(S)-3-hydroxydecanoyl-CoA + NAD+ <=> 3-oxodecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
BRENDA:
BS188068
KEGG:
R04743
MetaCyc:
RXN-12490
SABIO-RK:
4399
|
|
|
|
acetyl-CoA <=> acetoacetyl-CoA + CoA
|
1.1.1.34
hydroxymethylglutaryl-CoA reductase (NADPH)
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
–
–
|
| |
BRENDA:
BR44092
KEGG:
R00238
MetaCyc:
ACETYL-COA-ACETYLTRANSFER-RXN
SABIO-RK:
531
|
|
|
|
(3S)-3-hydroxytetradecanoyl-CoA + NAD+ <=> 3-oxotetradecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
KEGG:
R04739
MetaCyc:
RXN-12507
SABIO-RK:
4395
|
|
|
|
an_aldehyde + 1,4-benzoquinone + H2O <=> fatty_acid + hydroquinone
|
1.2.5.2
aldehyde dehydrogenase (quinone)
|
–
|
| |
KEGG:
R10912
|
|
|
|
glutaryl-CoA + FAD <=> crotonyl-CoA + CO2 + FADH2
|
1.3.8.6
glutaryl-CoA dehydrogenase (ETF)
|
–
|
| |
BRENDA:
BS413390
KEGG:
R02487
SABIO-RK:
2417
|
|
|
|
(S)-3-hydroxyhexanoyl-CoA + NAD+ <=> 3-oxohexanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
BRENDA:
BS188067
KEGG:
R04748
MetaCyc:
RXN-12570
SABIO-RK:
4404
|
|
|
|
(S)-3-hydroxyhexanoyl-CoA <=> trans-2-hexenoyl-CoA + H2O
|
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
–
|
| |
BRENDA:
BS2101
KEGG:
R04749
MetaCyc:
RXN-12567;
RXN-20677
SABIO-RK:
4405
|
|
|
|
lauroyl-CoA + FAD <=> trans-2-dodecenoyl-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.8.8
long-chain acyl-CoA dehydrogenase
1.3.99
|
–
–
–
–
|
| |
KEGG:
R03857
SABIO-RK:
3607
|
|
|
|
(3S)-hydroxyhexadecanoyl-CoA + NAD+ <=> 3-ketohexadecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
BRENDA:
BR50824
KEGG:
R04737
MetaCyc:
1.1.1.211-RXN;
RXN-14271
SABIO-RK:
4393
|
|
|
|
CoA + Glutarate + ATP <=> glutaryl-CoA + phosphate + ADP
|
6.2.1.6
glutarate---CoA ligase
|
–
|
| |
BRENDA:
BR89
KEGG:
R02402
MetaCyc:
GLUTARATE--COA-LIGASE-RXN
|
|
|
|
hexanoyl-CoA + FAD <=> trans-2-hexenoyl-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
1.3.8.1
short-chain acyl-CoA dehydrogenase
1.3.8.4
isovaleryl-CoA dehydrogenase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.8.8
long-chain acyl-CoA dehydrogenase
1.3.99
|
–
–
–
–
–
–
|
| |
BRENDA:
BS414702
KEGG:
R04751
SABIO-RK:
4407
|
|
|
|
(S)-3-hydroxybutyryl-CoA + NAD+ <=> acetoacetyl-CoA + NADH + H+
|
1.1.1.178
3-hydroxy-2-methylbutyryl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
1.1.1.36
acetoacetyl-CoA reductase
|
–
–
–
|
| |
BRENDA:
BS188053
KEGG:
R01975
MetaCyc:
RXN-11662
SABIO-RK:
2018
|
|
|
|
(S)-3-hydroxybutyryl-CoA <=> H2O + crotonyl-CoA
|
1.3.8.7
medium-chain acyl-CoA dehydrogenase
4.2.1.116
3-hydroxypropionyl-CoA dehydratase
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
|
–
–
–
–
|
| |
BRENDA:
BR51003
KEGG:
R03026
MetaCyc:
RXN-11667;
RXN-15014
SABIO-RK:
2876
|
|
